Record Details

Title Oxygen Isotopic Evidence of Water-Rock Interactions in the Coso Geothermal System
Authors Thomas ETZEL, John BOWMAN, Jesse MCCULLOCH, Joseph MOORE, Micheal SPICUZZA, John VALLEY
Year 2013
Conference Stanford Geothermal Workshop
Keywords oxygen isotope, permiability, water-rock interaction, Coso
Abstract The Coso geothermal system, located on the Naval Air Weapons Station, China Lake, California, is developed in a series of Mesozoic granitic and dioritic intrusions. Oxygen isotope measurements on a suite of whole rock samples from wells 33A-7, 68-6 and 73-19 in a high temperature section of the Coso system have revealed varying degrees of 18O/16O depletion from primary igneous δ18O values of 7.5 ‰ down to δ18O values of -4.60 ‰. Near surface whole-rock δ18O values range from +3.7 to +7.6 ‰. Whole-rock δ18O values decrease with depth in all three wells analyzed, with wells 33A-7 and 68-6 having more systematic trends. Whole-rock δ18O values for 33A-7 decrease from 7.6 ‰ near the surface to a minimum of -3.0 ‰ at a depth of 2530 m, then rapidly increase to values between 4 and 5 ‰ down to the base of the well at 3295 m. In well 68-6, whole-rock δ18O values decrease from 7.6 ‰ near the surface to a minimum value of -4.6 ‰ at a depth of 1411 m. In well 73-19 18O/16O depletion is generally less (minimum δ18O = 2.4 ‰), and δ18O values decrease less systematically with increasing depth. The lowest δ18O values in these wells are interpreted to represent alteration zones with higher water/rock ratios, most likely resulting from fracture-controlled increases in rock permeability. In the zones of maximum 18O/16O depletion in wells 33A-7 and 68-6, measured Δr-w fractionations are smaller than equilibrium Δr-w fractionation factors at current temperatures, suggesting that these portions of the Coso geothermal system were hotter and/or characterized by higher permeability in the past. However in well 73-19, measured Δr-w is larger than equilibrium Δr-w at current temperature conditions and the extent of 18O/16O depletion in whole-rock samples is generally smaller than in 33A-7 and 68-6. These differences suggest that isotope exchange in well 73-19 was more limited, either from kinetic barriers or lower permeability (less fluid access) or both.
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